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Organic stereochemistry Michael J.T. Robinson.

Por: Series Oxford chemistry primersDetalles de publicación: Oxford University Press 2002.Descripción: 89 p. ill. 25 cmISBN:
  • 0198792751
Tema(s): Clasificación LoC:
  • QD481 .R65 2002
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A short historical introduction serves to introduce many common stereochemical terms used throughout the book. Chapter two is an account of the structures of simple unstrained organic molecules followed by examples of strained molecules. The third chapter deals with conformational analysis of acyclic and carbocyclic molecules, ending with a short exposition of molecular mechanics. Chapter four is about stereoisomerism in molecules and compounds. A full description of enantiomerism and diastereomerism is followed by an explanation of the nomenclature for absolute and relative configurations of molecules and for topism. A short chapter describes racemates, their resolution, and methods for determining enantiomeric purity. The book concludes with a survey of stereoselective and stereospecific reactions, including the use of chiral catalysts and auxiliaries, rules for predicting stereoselectivity, and double asymmetric synthesis.

Includes bibliographical references and index.

Tabla de contenidos provista por Syndetics

  • 1 Introduction: Developments of methods and concepts in organic stereochemistry(p. 1)
  • 2 Organic molecules: shapes, sizes and strain(p. 5)
  • Problems(p. 20)
  • 3 The changing shapes of organic molecules(p. 21)
  • Problems(p. 36)
  • 4 Stereoisomerism in molecules and compounds(p. 37)
  • Problems(p. 57)
  • 5 Racemates and resolution(p. 59)
  • 6 Stereospecific and stereoselective reactions(p. 66)
  • Problems(p. 85)
  • Problems: answers and hints(p. 86)
  • Index(p. 88)

Notas de autor provistas por Syndetics

Michael J. T. Robinson is a University Lecturer in Organic Chemistry at Magdalen College, University of Oxford and works in the Dyson Perrins Laboratory, Oxford.
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