02915nam a22002655i 450000100090000000300040000900500170001300800410003002000180007104000230008904200080011205000240012010000300014424500770017425000170025126400430026830000460031133600260035733700280038333800270041150000230043850400470046150514280050852007130193619256806OSt20190822144754.0160831s2018 mau 000 0 eng  a9781305580350 aDLCbengerdacDLC apcc04aQD251.2b.B764 20181 aBrown, William H.eauthor10aOrganic chemistry /cWilliam H. Brown, Brent L. Iverson, Eric V. Anslyn. a8th edition. 1aBoston, MA :bCengage Learning,c2018. axxx, 1302 pages :billustrations ; 28 cm. atextbtxt2rdacontent aunmediatedbn2rdamedia avolumebnc2rdacarrier aIncludes glossary. aIncludes bibliographical references index. a1. Covalent Bonding and Shapes of Molecules -- 2. Alkanes and Cycloalkanes -- 3. Stereochemistry and Chirality -- 4. Acids and Bases -- 5. Alkenes -- 6. Reactions of Alkenes -- 7. Alkynes -- 8. Haloalkanes, Halogenation, and Radical Reactions -- 9. Nucleophilic Substitution and β-Elimination -- 10. Alcohols -- 11. Ethers, Epoxides, and Sulfides -- 12. Infrared Spectroscopy -- 13. Nuclear Magnetic Resonance Spectroscopy -- 14. Mass Spectrometry -- 15. Introduction to Organometallic Compounds -- 16. Aldehydes and Ketones -- 17. Carboxylic Acids -- 18. Functional Derivatives of Carboxylic Acids -- 19. Enolate Anions and Enamines -- 20. Dienes, Conjugated Systems, and Pericyclic Reactions -- 21. Benzene and the Concept of Aromaticity -- 22. Reactions of Benzene and Its Derivatives -- 23. Amines -- 24. Catalytic Carbon-Carbon Bond Formation -- 25. Carbohydrates -- 26. Lipids -- 27. Amino Acids and Proteins -- 28. Nucleic Acids -- 29. Organic Polymer Chemistry -- Appendices: 1. Thermodynamics and the Equilibrium Constant -- 2. Major Classes of Organic Acids -- 3. Bond Dissociation Enthalpies -- 4. Characteristic 1H-NMR Chemical Shifts -- 5. Characteristic 13C Chemical Shifts -- 6. Characteristic Infrared Absorption Frequencies -- 7. Electrostatic Potential Maps -- 8. Summary of Stereochemical Terms -- 9. Summary of the Rules of Nomenclature -- 10. Organic Chemistry Reaction Roadmaps -- Glossary -- Index.  aORGANIC CHEMISTRY is a student-friendly, cutting edge introduction for chemistry, health, and the biological sciences majors. The Eighth Edition builds on unified mechanistic themes, focused problem-solving, applied pharmaceutical problems, and biological examples. Stepwise reaction mechanisms emphasize similarities among mechanisms using four traits: breaking a bond, making a new bond, adding a proton, and taking a proton away. Pull-out organic chemistry reaction roadmaps designed stepwise by chapter help students devise their own reaction pathways. Emphasizing “how-to” skills, this edition is packed with challenging synthesis problems, medicinal chemistry problems, and unique roadmap problems.