Spins in chemistry [by] R. McWeeny.
Series Current chemical conceptsDetalles de publicación: New York Academic Press 1970.Descripción: xi, 153 p. illus. 21 cmISBN:- 0124867502
- 541/.28
- QD462 .M29
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A Polytechnic Press of the Polytechnic Institute of Brooklyn book.
Based on a series of lectures given during March 1969 at the Polytechnic Institute of Brooklyn.
Includes bibliographies.
Tabla de contenidos provista por Syndetics
- Preface(p. vii)
- Lecture 1. The Origin and Development of the Spin Concept(p. 1)
- The Stern-Gerlach Experiment(p. 2)
- The Formulation of Quantum Mechanics(p. 4)
- Expectation Values and Eigenvalues(p. 8)
- Properties of the Spin Operators(p. 10)
- Spin and Antisymmetry(p. 13)
- Spin and Magnetism(p. 16)
- Lecture 2. Spin and Valence(p. 23)
- Valence Bond Theory(p. 30)
- Difficulties and Developments(p. 38)
- Concluding Remarks(p. 42)
- References(p. 45)
- Lecture 3. The Origin of Spin Hamiltonians: A Simple Example(p. 47)
- The Dirac Equation(p. 47)
- The Breit Equation and Its Reduction(p. 50)
- The Spin Hamiltonian: Free Atom(p. 53)
- Effect of Crystal Fields(p. 55)
- The Effective Hamiltonian(p. 57)
- Detailed Solution(p. 59)
- The Spin Hamiltonian(p. 63)
- Experimental Implications(p. 64)
- References(p. 65)
- Lecture 4. Spin Density, Spin Populations, and Spin Correlation(p. 67)
- Electron Density Functions(p. 68)
- Spin Density(p. 76)
- Population Analysis(p. 80)
- Spin Correlation(p. 85)
- References(p. 89)
- Lecture 5. Nuclear Hyperfine Effects and Electron Spin-Spin Coupling(p. 91)
- A Simple Spin Hamiltonian(p. 92)
- General Theory(p. 93)
- Contact Hyperfine Coupling(p. 98)
- Electron Spin-Spin Coupling(p. 106)
- References(p. 109)
- Lecture 6. The g Tensor, Chemical Shifts, Nuclear Spin-Spin Coupling(p. 111)
- The g Tensor(p. 111)
- Chemical Shifts(p. 115)
- Nuclear Spin-Spin Coupling(p. 121)
- Conclusion(p. 125)
- References(p. 127)
- Appendix The Interaction of Two Electronic Systems(p. 129)
- General Theory(p. 130)
- Applications(p. 135)
- Nondegenerate Case(p. 136)
- Degenerate Case(p. 141)
- Conclusion: Charge Density Changes in Colliding Systems(p. 143)
- References(p. 148)
- Author Index(p. 149)
- Subject Index(p. 151)