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The Anomeric effect and associated stereoelectronic effects Gregory R.J. Thatcher, editor.

Colaborador(es): Series ACS symposium series ; 539Detalles de publicación: Washington, DC American Chemical Society 1993.Descripción: xi, 305 p. ill. 24 cmISBN:
  • 0841227292 (acid-free paper)
Tema(s): Clasificación CDD:
  • 541.2/252 20
Clasificación LoC:
  • QD471 .A56 1993
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Descripciones mejoradas de Syndetics:

Discusses contemporary experimental and computational studies on the anomeric effect and related stereoelectronic effects and presents conflicting data and theories in this highly controversial area. Explores applications in carbohydrate chemistry, including enzymology, as well as organometallic chemistry and the chemistry of phosphates and sulfates. Includes examination of molecular modeling methods in compounds influenced by stereoelectronic effects.

"Developed from a symposium sponsored by the Division of Carbohydrate Chemistry at the 204th National Meeting of the American Chemical Society, Washington, DC, August 23-28, 1992."

Includes bibliographical references and indexes.

Tabla de contenidos provista por Syndetics

  • Anomeric Effect: How It Came To Be Postulated
  • Anomeric and Associated Stereoelectronic Effects: Scope and Controversy
  • Intramolecular Strategies and Stereoelectronic Effects: Glycosides and Orthoesters Hydrolysis Revisited
  • Anomeric and Gauche Effects: Some Basic Stereoelectronics
  • Anomeric Effects: An Iconoclastic View
  • No Kinetic Anomeric Effect in Reactions of Acetal Derivatives
  • Involvement of ns* Interactions in Glycoside Cleavage
  • X-C-Z Anomeric Effect and Y-C-C-Z Gauche Effect (X,Y = O,S; Z = O,N): Evaluation of the Steric, Electrostatic, and Orbital Interaction Components
  • Origin and Quantitative Modeling of Anomeric Effect
  • Application of Quantum Theory of Atoms in Molecules to Study of Anomeric Effect in Dimethoxymethane
  • Anomeric and Reverse Anomeric Effect in Acetals and Related Functions
  • Glycosylmanganese Complexes and Anomeric Anomalies: The Next Generation?
  • Do Stereoelectronic Effects Control the Structure and Reactivity of Trigonal- Bipyramidal Phosphoesters?
  • Stereoelectronic Effects in Pentaoxysulfuranes: Putative Intermediates in Sulfuryl-Group Transfer
  • O-C-N Anomeric Effect in Nucleosides: A Major Factor Underlying the Experimentally Observed Eastern Barrier to Pseudorotation
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